I would be really cool to experience the series just from one character's POV, then another's and so on. I'm not sure I have the dedication for that though!
This is why I end up re-reading a lot of my favorite books, because the first time through I tend to fixate on some characters and skim over others. I was SO MAD on my first WoT read to realize the Seanchan were going to have a major role and I would have to go back and actually pay attention...